The nanomechanical properties of a CoCrMo medical implant alloy and a novel microtextured carbide-coated CoCrMo alloy (MTCC) surface—hardness and elastic modulus—were examined using nanoindentation. The MTCC surfaces may be a successful alternative bearing material for artificial joints. Understanding the nanomechanical, material properties, and surface morphology of the MTCC–CoCrMo surface are important for designing wear resistant artificial joints. The microtextured carbide surfaces were created using a microwave plasma-assisted chemical vapor deposition reaction (MPCVD). Nanomechanical properties, volumetric wear properties, and surface morphology were measured and used to determine the performance of the conventional CoCrMo alloy and MTCC surfaces (processed for either 2 or 4 h) in static environments and under severe wear conditions. The hardness, elastic modulus, and surface parameters of the 4-h MTCC surfaces were always greater than the 2-h MTCC and CoCrMo alloy surfaces. The nanomechanical properties changed for the CoCrMo alloy and 2-h and 4-h MTCC surfaces after, in contrast to before, wear testing. This indicates that the wear mechanisms affect the nanomechanical results. Overall, the 4-h MTCC surfaces had greater wear resistance than the 2-h MTCC or CoCrMo alloy surfaces.

References

3.
Chan
,
F. W.
,
Bobyn
,
J. D.
,
Medley
,
J. B.
,
Krygier
,
J. J.
,
Yue
,
S.
, and
Tanzer
,
M.
,
1996
, “
Engineering Issues and Wear Performance of Metal on Metal Hip Implants
,”
Clin. Orthop. Relat. Res.
,
333
, pp.
96
107
.10.1097/00003086-199612000-00009
4.
Tipper
,
J. L.
,
Firkins
,
P. J.
,
Ingham
,
E.
,
Fisher
,
J.
,
Stone
,
M. H.
, and
Farrar
,
R.
,
1999
, “
Quantitative Analysis of the Wear and Wear Debris From Low to High Carbon Content Cobalt Alloys Used in Metal on Metal Total Hip Replacements
,”
J. Mater. Sci.: Mater. Med.
,
10
, pp.
353
362
.10.1023/A:1026473723777
5.
Goldsmith
,
A. A.
,
Dowson
,
D.
,
Isaac
,
G. H.
, and
Lancaster
,
J. G.
,
2000
, “
A Comparative Joint Simulator Study of the Wear of Metal-on-Metal and Alternative Material Combinations in Hip Replacements
,”
Proc. Inst. Mech. Eng. H
,
214
(
1
), pp.
39
47
.10.1243/0954411001535228
6.
Dowson
,
D.
,
2001
, “
New Joints for the Millennium: Wear Control in Total Replacement Hip Joints
,”
Proc. Inst. Mech. Eng. H
,
215
, pp.
335
358
.10.1243/0954411011535939
7.
Villermaux
,
R.
,
2000
, “
Zirconia-Alumina as the New Generation of Ceramic-Ceramic THP: Wear Performance Evaluation Including Extreme Life Conditions
,”
Transactions of the Sixth World Biomaterials Congress
, p.
878
.
8.
Affatato
,
S.
,
Frigo
,
M.
, and
Toni
,
A.
,
2000
, “
An In Vitro Investigation of Diamond-Like Carbon as a Femoral Head Coating
,”
J. Biomed. Mater. Res.
,
53
, pp.
221
226
.10.1002/(SICI)1097-4636(2000)53:3<221::AID-JBM6>3.0.CO;2-Z
9.
Wisbey
,
A.
,
Gregson
,
P. J.
, and
Tuke
,
M.
,
1987
, “
Application of PVD TiN Coating to CoCrMo Based Surgical Implants
,”
Biomaterials
,
8
, pp.
70
76
.10.1016/0142-9612(87)90085-8
10.
Klepper
,
C. C.
Williams
,
J. M.
,
Truhan
,
J. J.
,
Qu
,
J.
,
Riester
,
L.
,
Hazelton
,
R. C.
,
Moschella
,
J. J.
,
Blau
,
P. J.
,
Anderson
,
J. P.
,
Popoola
,
O. O.
, and
Keitz
,
M. D.
,
2008
, “
Tribo-Mechanical Properties of Thin Boron Coatings Deposited on Polished Cobalt Alloy Surfaces for Orthopedic Applications
,”
Thin Solid Films
,
516
(
10
), pp.
3070
3080
.10.1016/j.tsf.2007.10.111
11.
Anthony
,
K. C.
,
1993
, “
Wear-Resistant Cobalt-Base Alloys
,”
J. Metals
,
52
, pp.
52
60
.
12.
Black
,
J.
,
1992
,
Biological Performance of Materials: Fundamentals of Bio-compatibility
,
Marcel Dekker
,
New York
.
13.
VanDamme
,
N. S.
,
Que
,
L.
, and
Topoleski
,
L. D. T.
,
1999
, “
Carbide Surface Coating of CoCrMo Implant Alloys by a Microwave Plasma-Assisted Reaction
,”
J. Mater. Sci.
,
34
, pp.
3523
3531
.10.1023/A:1004670207579
14.
VanDamme
,
N. S.
, and
Topoleski
,
L. D. T.
,
2005
, “
Control of Surface Morphology of Carbide Coating on Co-Cr-Mo Implant Alloy
,”
J. Mater. Sci.: Mater. Med.
,
16
(
7
), pp.
647
654
.10.1007/s10856-005-2536-2
15.
VanDamme
,
N. S.
,
Wayman
,
B. H.
, and
Topoleski
,
L. D. T.
,
2003
, “
Wear Behavior of Carbide Coated Co-Cr-Mo Implant Alloy
,”
J. Mater. Sci.: Mater. Med.
,
14
(
1
), pp.
47
53
.10.1023/A:1021549403641
16.
Ettienne-Modeste
,
G.
, and
Topoleski
,
T.
,
2010
, “
Viscous Behavior of Different Concentrations of Bovine Calf Serum Before and After Wear Testing
,”
IFMBE Proc.
,
32
, pp.
161
164
.10.1007/978-3-642-14998-6
17.
McKellop
,
H.
,
Park
,
S. H.
, and
Chiesa
,
R.
,
1996
, “
In Vivo Wear of 3 Types of Metal on Metal Hip Prostheses. 3. Changes in Alloy Microstructure Do Not Appear to During 2 Decades of Use
,”
Clin. Orthop.
,
329
(
Suppl
), pp.
128
140
.10.1097/00003086-199608001-00013
18.
Oliver
,
W. C.
, and
Pharr
,
G. M.
,
1992
, “
An Improved Technique for Determining Hardness and Elastic Modulus Using Load and Displacement Sensing Indentation Experiments
,”
J. Mater. Res.
,
7
, pp.
1564
1583
.10.1557/JMR.1992.1564
19.
Ettienne-Modeste
,
G.
,
2010
, “
Wear and Mechanical Characterization of the Micro-Textured Carbide CoCrMo Alloy Surface
,”
56th Annual Meeting of the Orthopaedic Research Society
.
20.
Timoshenko
,
S. P.
, and
Goodier
,
J. N.
,
1970
,
Theory of Elasticity
, 3rd ed.
McGraw-Hill
,
New York
, p.
412
.
21.
Hupp
,
S. J.
, and
Hart
,
D. P.
,
2004
, “
Experimental Method for Frictional Characterization of Micro-textured Surfaces
,”
Proceedings of the ASME/STLE International Joint Tribology Conference, IJTC
, pp.
1655
1660
.
22.
Akamatsu
,
Y.
,
Tsushima
,
N.
,
Goto
,
T.
,
Hibi
,
K.
, and
Itoh
,
K.
,
1991
, “
Source Improvement of Roller Bearing Fatigue Life by Surface Roughness Modification
,” SAE Technical Paper No. 910958.
23.
Bhushan
,
B.
,
2005
, “
Biomimetic Surface May Solve MEMS Friction Problem
,”
Mater. Technol.
,
20
(
1
), pp.
55
56
.
24.
Bhushan
,
B.
,
2001
, “
Nano-to-Microscale Wear and Mechanical Characterization Using Scanning Probe Microscopy
,”
Wear
,
251
, pp.
1105
1123
.10.1016/S0043-1648(01)00804-3
25.
Chilamakuri
,
S. K.
, and
Bhushan
,
B.
,
1997
, “
Optimization of Asperities for Laser-Textured Magnetic Disk Surfaces
,”
Tribol. Trans.
,
40
(
2
), pp.
303
311
.10.1080/10402009708983659
26.
Yao
,
J. Q.
,
Laurent
,
M. P.
,
Johnson
,
T. S.
,
Blanchard
,
C. R.
, and
Crowninshield
R. D.
,
2003
, “
The Influences of Lubricant and Material on Polymer/CoCr Sliding Friction
,”
Wear
,
255
(
1–6
), pp.
780
784
.10.1016/S0043-1648(03)00180-7
27.
Wang
,
A.
,
Essner
,
A.
,
Polineni
, V
. K.
,
Stark
,
C.
, and
Dumbleton
,
J. H.
,
1998
, “
Lubrication and Wear of Ultra-high Molecular Weight Polyethylene in Total Joint Replacements
,”
Tribol. Int.
,
31
(
1–3
), pp.
17
33
.10.1016/S0301-679X(98)00005-X
28.
Gispert
,
M. P.
,
Serro
,
A. P.
,
Colaco
,
R.
, and
Saramago
,
B.
,
2006
, “
Friction and Wear Mechanisms in Hip Prosthesis: Comparison of Joint Materials Behavior in Several Lubricants
,”
Wear
,
260
(
1–2
), pp.
149
158
.10.1016/j.wear.2004.12.040
29.
Wang
,
A.
,
Essner
,
A.
, and
Schmidig
,
G.
,
2004
, “
The Effects of Lubricant Composition on in Vitro Wear Testing of Polymeric Acetabular Components
,”
J. Biomed. Mater. Res. Part B: Appl. Biomater.
,
68B
, pp.
45
52
.10.1002/jbm.b.10077
30.
Unsworth
,
A.
,
1978
, “
The Effects of Lubrication in Hip Joint Prostheses
,”
Phys. Med. Biol.
,
23
, pp.
253
268
.10.1088/0031-9155/23/2/004
31.
Aurora
,
A.
,
DesJardins
,
J. D.
,
Joseph
,
P. F.
, and
LaBerge
,
M.
,
2006
, “
Effect of Lubricant Composition on the Fatigue Properties of Ultra-High Molecular Weight Polyethylene for Total Knee Replacement
,”
Proc. Inst. Mech. Eng., Part H: J. Eng. Med.
,
220
(
Part H
), pp.
541
551
.10.1243/09544119JEIM35
32.
Chan
,
F. W.
,
Bobyn
,
J. D.
,
Medley
,
J. B.
,
Krygier
,
J. J.
, and
Tanzer
,
M.
,
1999
, “
The Otto Aufranc Award. Wear and Lubrication of Metal-on-Metal Hip Implants
,”
Clin. Orthop. Relat. Res.
,
369
, pp.
10
24
.10.1097/00003086-199912000-00003
33.
Scholes
,
S. C.
, and
Unsworth
,
A.
,
2006
, “
The Effects of Proteins on the Friction and Lubrication of Artificial Joints
,”
Proc. Inst. Mech. Eng., Part H: J. Eng. Med.
,
220
(
Part H
), pp.
687
691
.10.1243/09544119JEIM21
You do not currently have access to this content.