Effects of insoluble surfactant on the dynamic rupture of a thin liquid film coated on a flat plate are studied. The strong nonlinear evolution equations derived by the integral method are solved by numerical method. The results show that enhancing (weakening) the Marangoni effect (the surface diffusion effect) will delay the rupture process. Furthermore, the rupture time predicted by the integral theory is shorter than that predicted by the long-wave expansion method. In addition, the quantitative difference in the rupture time predicted by two models enlarges with the increase of Marangoni effect, however, without obvious change as the diffusion effect increases.

1.
Alekseenko
S. V.
,
Narkoryakov
V. Ye.
, and
Pokusaev
B. G.
,
1991
, “
Wave Formation on a Vertical Falling Liquid Film
,”
AIChE Journal
, Vol.
31
, pp.
1446
1460
.
2.
Borgas
M. S.
, and
Grotberg
J. B.
,
1988
, “
Monolayer Flow on a Thin Film
,”
Journal of Fluid Mechanics
, Vol.
193
, pp.
151
176
.
3.
Burelbach
J. P.
,
Bankoff
S. G.
, and
Davis
S. H.
,
1988
, “
Nonlinear Stability of Vaporizing/condensing Liquid Films
,”
Journal of Fluid Mechanics
, Vol.
195
, pp.
463
494
.
4.
Chen
J. L.
, and
Hwang
C. C.
,
1994
, “
Effects on Inertia on the Process of a Thin Liquid Film
,”
Journal of Sciences Colloid Interface
, Vol.
167
, pp.
214
216
.
5.
De Wit
A.
,
Gallez
D.
, and
Christov
C. I.
,
1994
, “
Nonlinear Evolution Equation for Thin Liquid Films with Insoluble Surfactant
,”
Physics of Fluids
, Vol.
6
, pp.
3256
3266
.
6.
Erneux
T.
, and
Davis
S. H.
,
1993
, “
Nonlinear Rupture of Free Films
,”
Physics of Fluids A
, Vol.
5
, p.
1117
1117
.
7.
Gaver
D. P.
, and
Grotberg
J. B.
,
1990
, “
The Dynamics of a Localized Surfactant on a Thin Film
,”
Journal of Fluid Mechanics
, Vol.
213
, pp.
127
148
.
8.
Gaver
D. P.
, and
Grotberg
J. B.
,
1992
, “
Droplet Spreading on a Thin Viscous Film
,”
Journal of Fluid Mechanics
, Vol.
235
, pp.
399
414
.
9.
Hwang
C. C.
,
Chang
S. H.
and
Chen
J. L.
,
1993
, “
On the Rupture Process of Thin Liquid Film
,”
Journal of Sciences Colloid Interface
, Vol.
159
, pp.
184
216
.
10.
Hwang
C. C.
,
Chen
J. L.
, and
Shen
L. F.
,
1996
, “
Strong Nonlinear Dynamic Rupture Theory of Thin Liquid Film
,”
Physics Review E
, Vol.
54
, pp.
3013
3016
.
11.
Hwang
C. C.
,
Chen
J. L.
, and
Shen
L. F.
,
1996
, “
Nonlinear Rupture Theory of a Thin Free Liquid Film with Insoluble Surfactant
,”
Journal of Physical Society Japan
, Vol.
65
, pp.
2494
2501
.
12.
Jensen
O. E.
, and
Grotberg
J. B.
,
1992
, “
Insoluble Surfactant Spreading on a Thin Viscous Film: Shock Evolution and Film Rupture
,”
Journal of Fluid Mechanics
, Vol.
240
, pp.
259
288
.
13.
Jensen
O. E.
and
Grotberg
J. B.
,
1993
, “
The Spreading of Heat or Soluble Surfactant Along a Thin Liquid Film
,”
Physics of Fluids A
, Vol.
5
, pp.
58
68
.
14.
Prokopiou
Th.
,
Cheng
M.
, and
Chang
H. C.
,
1991
, “
Long waves on inclined films at high Reynolds number
,”
Journal of Fluid Mechanics
, Vol.
222
, pp.
665
691
.
15.
Ruckemstein
E.
and
Jain
R. K.
,
1974
, “
Spontaneous rupture of thin liquid film
,”
Journal of Chemical Society Far. Transactions II
, Vol.
70
, pp.
132
147
.
16.
Sheludko
A.
,
1967
, “
Thin liquid film
,”
Advanced Sciences Colloid Interface
, Vol.
1
, pp.
391
494
.
17.
Troian
S. M.
,
Herbolzheimer
E.
and
Safra
S. A.
,
1990
, “
Model for the Fingering Instability Spreading Surfactant Drops
,”
Physics Review Letters
, Vol.
65
, pp.
333
336
.
18.
Williams
M. B.
, and
Davis
S. H.
,
1982
, “
Nonlinear Theory of Film Rupture
,”
Journal of Sciences Colloid Interface
, Vol.
90
, pp.
220
228
.
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