In multicomponent gaseous flows with chemical reactions, diffusion is usually considered to be a single-source entropy generator. Introducing the concept of dispersion, where the atom balance is dominant rather than the molecular, shows in an ideal setting that, even when there is diffusion, the dispersion part of entropy generation can be reduced to zero by proper choice of species flow velocities. Fuel cells and methane reformers are employed as examples to illustrate these concepts.
Issue Section:
Technical Papers
1.
Call
F. W.
1996
, “Thermodynamic Analysis of High Temperature Fuel Cells: Methane Reforming
,” Systems Division
, ASME AES-Vol. 36
, pp. 305
–311
.2.
Dunbar
W. R.
Lior
N.
Gaggioli
R. A.
1992
, “The Component Equations of Energy and Exergy
,” ASME JOURNAL OF ENERGY RESOURCES TECHNOLOGY
, Vol. 114
, pp. 75
–83
.3.
EES (Ver. 4.314W), F-Chart Software, 4406 Foxbluff Rd., Middletown, WI 53562.
4.
Gaggioli
R. A.
Dunbar
W. R.
1993
, “Emf, Maximum Power and Efficiency of Fuel Cells
,” ASME JOURNAL OF ENERGY RESOURCES TECHNOLOGY
, Vol. 115
, pp. 100
–104
.5.
Gyftopoulos, E. P., and Beretta, G. P., 1992, “Entropy Generation Rate in a Chemically Reacting System,” Proceedings, Thermodynamics and the Design, Analysis, and Improvement of Energy Systems, ASME AES-Vol. 27/HTD-Vol. 228, pp. 329–334.
6.
Gyftopoulos, E. P., Flik, M. I., and Beretta, G. P., 1992, “What is Diffusion?,” Proceedings, Thermodynamics and the Design, Analysis, and Improvement of Energy Systems, ASME AES-Vol. 27/HTD-Vol. 228, pp. 335–340.
7.
Marle
C. M.
1982
, “On Macroscopic Equations Governing Multiphase Fluid Flow with Diffusion and Chemical Reactions in Porous Media
,” Engineering Science
, Vol. 20
, pp. 643
–662
.8.
Teng
H.
Kinoshita
C. M.
Masutani
S. M.
1996
, “Entropy Generating in Multicomponent Reacting Fluid Flow with Heat and Mass Transfer
,” ASME
AES-Vol. 36
, pp. 191
–198
.
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