Suitable porous electrode design may play a significant role in the performance enhancement of solid oxide fuel cells (SOFCs). In this paper a genetic algorithm optimization method is employed to design electrodes based on a 2D planar SOFC model development. The objective is to find suitable porosities and particle sizes distributions for both anode and cathode electrodes so that the cell performance can be maximized. The results indicate that the optimized heterogeneous morphology may better improve SOFC performance than the homogeneous counterpart, particularly under relatively high current density conditions. The optimization results are dependent on the operating conditions. The effects of inlet mass flow rates and fuel compositions are investigated. The proposed approach provides a systematical method for electrode microstructure designs of high performance SOFCs.

References

1.
Minh
,
N.
, 2004, “
Solid Oxide Fuel Cell Technology-Features and Applications
,”
Solid State Ionics
,
174
, pp.
271
277
.
2.
Liu
,
Y.
,
Compson
,
C.
, and
Liu
,
M.
, 2004, “
Nanostructured and Functionally Graded Cathodes for Intermediate Temperature Solid Oxide Fuel Cells
,”
J. Power Sources
,
138
, pp.
194
198
.
3.
Cable
,
T. L.
, and
Sofie
,
S. W.
, 2007, “
A Symmetrical, Planar SOFC Design for NASA’s High Specific Power Density Requirements
,”
J. Power Sources
,
174
, pp.
221
227
.
4.
Xu
,
X.
,
Xia
,
C.
,
Xiao
,
G.
, and
Peng
,
K.
, 2005, “
Fabrication and Performance of Functionally Graded Cathodes for IT-SOFCs Based on Doped Ceria Electrolytes
,”
Solid State Ionics
,
176
, pp.
1513
1520
.
5.
Kakaç
,
S.
,
Pramuanjaroenkij
,
A.
, and
Zhou
,
X. Y.
, 2007, “
A Review of Numerical Modeling of Solid Oxide Fuel Cells
,”
Int. J. Hydrogen Energy
,
32
(
7
), pp.
761
786
.
6.
Costamagna
,
P.
,
Costa
,
P.
, and
Antonucci
,
V.
, 1998, “
Micro-modeling of Solid Oxide Fuel Cell Electrodes
,”
Electrochim. Acta
,
43
, pp.
375
394
.
7.
Jeon
,
D. H.
,
Nam
,
J. H.
, and
Kim
,
C. J.
, 2006, “
Microstructural Optimization of Anode-Supported Solid Oxide Fuel Cells by a Comprehensive Microscale Model
,”
J. Electrochem. Soc.
,
153
(
2
), pp.
A406
A417
.
8.
Deseure
,
J.
,
Bultel
,
Y.
,
Dessemond
,
L.
, and
Siebert
,
E.
, 2005, “
Theoretical Optimisation of a SOFC Composite Cathode
,”
Electrochim. Acta
,
50
, pp.
2037
2046
.
9.
Schneider
,
L. C. R.
,
Martin
,
C. L.
,
Bultel
,
Y.
,
Dessemond
,
L.
, and
Bouvard
,
D.
, 2007, “
Percolation Effects in Functionally Graded SOFC Electrodes
,”
Electrochim. Acta
,
52
, pp.
3190
3198
.
10.
Ni
,
M.
,
Leung
,
M. K. H.
, and
Leung
,
D. Y. C.
, 2007, “
Micro-scale Modeling of Solid Oxide Fuel Cells with Micro-structurally Graded Electrodes
,”
J. Power Sources
,
168
, pp.
369
378
.
11.
Greene
,
E. S.
,
Chiu
,
W. K. S.
, and
Medeiros
,
M. G.
, 2006, “
Mass Transfer in Graded Microstructure Solid Oxide Fuel Cell Electrodes
,”
J. Power Sources
,
161
, pp.
225
231
.
12.
Shi
,
J.
, and
Xue
,
X.
, 2010, “
CFD Analysis of a Symmetrical Planar SOFC With Heterogeneous Electrode Properties
,”
Electrochim. Acta
,
55
(
18
), pp.
5263
5273
.
13.
Ni
,
M.
,
Leung
,
M. K.H.
, and
Leung
,
D. Y. C.
, 2007, “
Parametric Study of Solid Oxide Fuel Cell Performance
,”
Energy Convers. Manage.
,
48
(
5
), pp.
1525
1535
.
14.
Nam
,
J. H.
, and
Jeon
,
D. H.
, 2006, “
A Comprehensive Micro-scale Model for Transport and Reaction in Intermediate Temperature Solid Oxide Fuel Cells
,”
Electrochim. Acta
,
51
(
17
), pp.
3446
3460
.
15.
Zhao
,
F.
, and
Virkar
,
A. V.
, 2005, “
Dependence of Polarization in Anode-Supported Solid Oxide Fuel Cells on Various Cell Parameters
,”
J. Power Sources
,
141
, pp.
79
95
.
16.
Holland
,
J.
, 1975,
Adaptation in Natural and Artificial Systems
,
University of Michigan Press
,
Ann Arbor, MI
.
17.
Gen
,
M.
, and
Cheng
,
R.
, 1999,
Genetic Algorithms and Engineering Optimization
,
Wiley-Interscience
,
New York
.
18.
Wildi-Tremblay
,
P.
, and
Gosselin
,
L.
, 2007, “
Layered Porous Media Architecture for Maximal Cooling
,”
Int. J. Heat Mass Transfer
,
50
, pp.
464
478
.
19.
Shi
,
J.
, and
Wang
,
J.
, 2008, “
Optimized Structure of Two Layered Porous Media With Genetic Algorithm for Transpiration Cooling
,”
Int. J. Therm. Sci.
,
47
(
12
), pp.
1595
1601
.
You do not currently have access to this content.